胡憾石  副教授，博士生导师

办公室：清华大学蒙民伟科技大楼南楼523

电话：010-62789229

Email：hshu@mail.tsinghua.edu.cn

ORCID：0000-0001-9508-1920

课题组网址：https://www.x-mol.com/groups/HanshiHU

工作履历

研究领域

相对论量子化学

镧系锕系元素理论计算化学

团簇理论计算化学

学术成果

代表性论文

1.G. Wang^#, J. Zhao^#, H. S. Hu^*, J. Li, M. F. Zhou^*, “Formation and Characterization of BeFe(CO)₄^- Anion with Beryllium-Iron Bonding” Angew. Chem. Int. Ed., 2021, doi.org/10.1002/anie.202015760.

2.Y. Xiao^#, X. K. Zhao^#, T. Wu, J. T. Miller, H. S. Hu^*, J. Li, W. Huang^*, P. L. Diaconescu^*, “Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes” Chem. Sci. 12, 227-238, (2021).

3.Y. Zheng^#, C. S. Cao^#, W. Ma^#, T. Chen, B. Wu, C. Yu, Z. Huang, J. Yin, H. S. Hu^*, J. Li, W. X. Zhang^*, Z. Xi, “2-Butene Tetraanion Bridged Dinuclear Samarium (III) Complexes via Sm (II)-Mediated Reduction of Electron-Rich Olefins” J. Am. Chem. Soc. 142, 10705-10714 (2020).

4.J. Q. Wang^#, C. X. Chi^#, H. S. Hu^*, Xiang. Li, M. Luo, J. Li, M. F. Zhou^*, “Multiple Bonding Between Group-3 Metals and Fe(CO)₃^-” Angew. Chem. Int. Ed., 59, 2344-2348, (2020).

5.C. X. Chi^#, J. Q. Wang^#, H. S. Hu^*, Y. Y. Zhang, W. L. Li, L. Meng, M. Luo, M. F. Zhou^*, J. Li^*, “Quadruple Bonding Between Iron and boron in the BFe(CO)₃^- Complexes” Nat. Commun., 10, 4713, (2019).

6.X. -M. Kang, H.-S. Hu^*, Z.-L. Zhu, J.-Q. Wang, P. Cheng, J. Li^*, B. Zhao^*, “An Ultrastable Matryoshka [Hf₁₃] Nanocluster as a Luminescent Sensor for Concentrated Alkali and Acid” Angew. Chem. Int. Ed., 131, 16763-16769 (2019).

7.H. Xu, C.-S. Cao, H.-S. Hu^*, S.-B. Wang, J.-C. Liu, P. Cheng, N. Kaltsoyannis^*, J. Li, B. Zhao^*, “High Uptake of ReO₄⁻ by a Radiation Resistant [Th₄₈Ni₆] Nanocage-Based Metal−Organic Framework” Angew. Chem. Int. Ed., 131, 6083-6088 (2019).

8.H.-C. Hu, P. Cui, H.-S. Hu^*, P. Cheng, J. Li, B. Zhao^*, “Stable Zn-I-Containing MOFs with Large [Zn-70] Nanocages from Assembly of Zn-II Ions and Aromatic [Zn₈(I)] Clusters”, Chem. Eur. J. 24, 3683-3688 (2018) (Cover).

9.Y. L. Wang, H. S. Hu^*, W. L. Li, F. Wei, J. Li^*, “Relativistic Effects Break Periodicity in Group 6 Diatomic Molecules”, J. Am. Chem. Soc. 138, 1126-1129 (2016).

10.H.-C. Hu^#, H.-S. Hu^#, B. Zhao, P. Cui, P. Cheng, J. Li, "Metal-Organic Frameworks (MOFs) of a Cubic Metal Cluster with Multi-Centered Mn(I)-Mn(I) Bonds", Angew. Chem. Int. Ed., doi: 10.1002/anie.201504758R1, (2015).

11.P. Cui^#, H. S. Hu^#, B. Zhao, J. T. Miller, P. Cheng, J. Li, “A Multicentre-bonded [Zn^I]₈ cluster with cubic aromaticity” , Nature Communications, DOI: 10.1038/ncomms7331, (2015).

12.H. S. Hu, F. Wei, X. Wang, L. Andrews, J. Li, “Actinide–Silicon Multiradical Bonding: Infrared Spectra and Electronic Structures of the Si(μ-X)AnF₃ (An= Th, U; X= H, F) Molecules”, J. Am. Chem. Soc. 136, 1427-1437 (2014).

13.H. S. Hu, K. Kowalski, “Excitation Energies with Cost-Reduced Variant of the Active-Space EOMCCSDT Method: The EOMCCSDt-3̅ Approach”, J. Chem. Theory Comput., 9(11), 4761-4768 (2013).

14.H. S. Hu, Y. H. Qiu, X. G. Xiong, W. H. E. Schwarz, J. Li, “On the maximum bond multiplicity of carbon: unusual C≣U quadruple bonding in molecular CUO”, Chem. Sci., 3(9), 2786-2796, (2012).