杨金东 副研究员
地址：北京市海淀区清华大学蒙民伟科技南楼s905室
TEl: 86-10-62787136
Email: jdyang@mail.tsinghua.edu.cn
教育背景
2005-2009年，南开大学化学系学士
2009-2014年，南开大学化学系博士
工作履历
2014-2017年，在南开大学化学系博士后
2017年10月-至今清华大学化学系副研究员
研究领域
研究兴趣：化学键能量学、键能的应用、反应机理研究。
奖励与荣誉
2019年 中国化学会物理有机化学新人奖
2019年 中国科协青年人才托举工程
2019年 北京市科协青年人才托举工程
2022年 国家自然科学基金委优秀青年基金
学术成果
代表性成果：
1. Yang, J.-D.; Cheng, J.-P.*; et al. Internet Bond-energy Databank (pKa and BDE)-iBonD: http://ibond.nankai.edu.cn.
2. Xue, J.; Zhang, Y.-S.; Huan, Z.; Luo, H.-T.; Dong, L.; Yang, J.-D.*; Cheng, J.-P., Phosphonium-Catalyzed Monoreduction of Bisphosphine Dioxides: Origin of Selectivity and Synthetic Applications. J. Am. Chem. Soc. 2024, 146, 9335-9346.
3. Xue, J.; Zhang, Y.-S.; Huan, Z.; Yang, J.-D.*; Cheng, J.-P., Deoxygenation of Phosphine Oxides by PIII/PV=O Redox Catalysis via Successive Isodesmic Reactions. J. Am. Chem. Soc. 2023, 145, 15589–15599.
4. Zhang, W.; Luo, H.-T.; Yang, J.-D.*, Breakthrough in phosphonylation of alkyl radicals: Alternative access of alkyl phosphonates. Chem 2023, 9, 2735-2737.
5. Wu, J.-Y.; Mo, B.-R.; Yang, J.-D.*; Cheng, J.-P.*, A Distinctive Pattern for Substituent Effects on Transition Metal Centers: Enhanced Electron-Donating Capacity of Cationic Palladium Species. CCS Chem. 2022, 5, 1163-1175.
6. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions. Nat. Commun. 2021, 12, 2835.
7. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, Recent progress in reactivity study and synthetic application of N-heterocyclic phosphorus hydrides. Natl. Sci. Rev. 2021, 8, nwaa253.
8. Wu, J.-Y.; Li, Z.; Yang, J.-D.*; Cheng, J.-P.*, Bonding Energetics of Palladium Amido/Aryloxide Complexes in DMSO: Implications for Palladium-Mediated Aniline Activation. Angew. Chem. Int. Ed. 2020, 59, 23782-23790.
9. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, Diazaphosphinyl radical-catalyzed deoxygenation of α-carboxy ketones: a new protocol for chemo-selective C–O bond scission via mechanism regulation. Chem. Sci. 2020, 11, 8476-8481.
10. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications. Chem. Sci. 2020, 11, 3672-3679.
11. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, Exploiting the radical reactivity of diazaphosphinanes in hydrodehalogenations and cascade cyclizations. Chem. Sci. 2020, 11, 4786-4790.
12. Luo, W.; Mao, C.; Ji, P.; Wu, J.-Y.; Yang, J.-D.*; Cheng, J.-P.*, Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C–H dissociation and insight into respective solvation. Chem. Sci. 2020, 11, 3365-3370.
13. Zhang, J.; Yang, J.-D.*; Cheng, J.-P.*, A Nucleophilicity Scale for the Reactivity of Diazaphospholenium Hydrides: Structural Insights and Synthetic Applications. Angew. Chem. Int. Ed. 2019, 58, 5983-5987.
14. Yang, J.-D.*; Xue, J.; Cheng, J.-P.*, Understanding the role of thermodynamics in catalytic imine reductions. Chem. Soc. Rev. 2019, 48, 2913-2926.
15. Zhang, J.#; Yang, J.-D.#; Zheng, H.; Xue, X.-S.*; Mayr, H.*; Cheng, J.-P.*, Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents. Angew. Chem. Int. Ed. 2018, 57, 12690-12695.
16. Yang, J.-D.#; Ji, P.#; Xue, X.-S.; Cheng, J.-P.*, Recent Advances and Advisable Applications of Bond Energetics in Organic Chemistry. J. Am. Chem. Soc. 2018, 140, 8611-8623.
