Dehua HE
Personal Data:
Dehua HE, Ph. D., Professor, Department of Chemistry, Tsinghua University
Address: Chemistry Building, Tsinghua University, Beijing, 100084 China
E-mail: hedeh@mail.tsinghua.edu.cn
Education:
lFrom Feb. 1978 to Jan.1982, Department of Petrochemical Technology, East China University of Science and Technology (Shanghai, China), obtained Bachelor degree in Jan. 1982.
lFrom Apr. 1985 to Mar. 1987, Division of Synthetic Chemistry, School of Chemical Engineering， Okayama University (Okayama, Japan), obtained Master degree in Mar. 1987.
lFrom Apr. 1987 to Mar. 1990, Division of Environmental Chemistry and Engineering, School of Science and Engineering, Tokyo Institute of Technology (Tokyo, Japan), received Ph. D. in Mar. 1990.
Research experience:
lFrom Apr. 1990 to Mar. 1991, Postdoctoral Fellow, Fujisawa Lab, Tokuyama Company (Fujisawa, Japan).
lFrom Apr. 1991 to Aug. 1994, Research Fellow, Sagami Chemical Research Center (Sagamihara, Japan).
lFrom Sep. 1994 to Aug. 1995, Postdoctoral Fellow, Department of Chemistry, Pekin University (Beijing, China).
lFrom Sep. 1995 to present, Associate Professor and Full Professor, Department of Chemistry, Tsinghua University (Beijing, China).
üFrom Apr. 1999 to March 2000, Visiting researcher, Research Institute of Innovative Technology for the Earth (Kyoto, Japan).
üFrom Nov. 2003 to May 2004, Visiting scholar, The University of Virginia (Virginia, USA).
Awards and Honours:
lMar. 1996, STA Fellow Award, STA, Japan.
lFeb. 1998, Award for Excellent Teacher–Tsinghua Zhi You from Motoluola Company, Tsinghua University, China (1997-1998).
lApr. 1999, AIST Visiting Researcher Award, AIST, Japan.
lNov. 2003, CSC Award for visiting USA, China Scholarship Council.
lJan. 2010, the second prize of the Natural Science Award of Ministry of Education, China (Award winning Project: Studies on Oxide Catalists and Nano-composite Metal/Oxide Catalists).
Professional societies:
lSenior Member of the Chinese Chemical Society
Professional activities:
lMember of Academic Committee of Coordination Catalysis of Chemical Society of China (2003 - 2017)
lEditorial board, Chinese Journal of fuel chemistry, China (1998-2004).
Research Interests:
Heterogeneous and homogeneous catalysis, catalysts and catalytic processes for C1 chemistry, clean fuel synthesis, CO2 utilization and bio-mass conversion to chemicals.
Research Subjects:
lCatalysts for converting glycerol and CO2 to glycerol carbonate
lCatalysts for synthesis of dimethyl carbonate from CO2 and methanol
lCatalysts for CO2 reforming of methane to syngas
lCatalysts for hydrogenolysis of glycerol to propanediols
lCatalysts for partial oxidation of methane to syngas
lCatalysts for isobutene synthesis from syngas
lCatalysts for the synthesis of C2-C4 alcohols from syngas
lHydroformylation of mixed octenes to C9-aldehydes
lImmobilization of Rh homogeneous catalysts for olefin hydroformylation
lAmorphous Co-B catalysts for olefin hydroformylation
Principal research grants (Project Leader)：
lNational Natural Science Foundation of China (Grant No. 21573120, 21073104, 20973098, 20673064, 20410202074 and 20373031)
lNational Program on Key Basic Research Project (973 Program, for clean and efficient conversion of coal, 2011CB201400) (Fifth Sub-Project, Grant No. 2011CB201405)
lNational High-tech R&D Program of China (863 Program, Special topics for clean coal technology) (Grant No. 2007AA05Z332)
lResearch Fund for the Doctoral Program of Higher Education of China (Grant No. 20973098, 2007003108)
lInternational cooperation project (China-South Korea)
Selected Publications (Peer reviewed):
lYajin Li, Huimin Liu*, Lan Ma, Jiaxiong Liu, Dehua He*, Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO2 over Au/Co3O4- ZnO Catalyst, Acta Phys. -Chim. Sin. 40 (9), 2308005, 2024.
lYuqiao Li, Yiming Lei, Dezheng Li, Aidi Liu, Ze Zheng, Huimin Liu*, Jiawen Guo, Siyu Liu, Chunnan Hao, Dehua He*, Recent Progress on Photocatalytic CO2 Conversion Reactions over Plasmonic Metal-based Catalysts, ACS Catalysis., 13, 10177-10204, 2023.
lHuimin Liu*, Dezheng Li, Jiawen Guo, Yuqiao Li, Aidi Liu, Yitong Bai, Dehua He*, Recent advances on catalysts for preferential oxidation of CO, Nano Research, 16(4), 4399-4410, 2023.
lJiawen Guo, Yiming Lei, Huimin Liu*, Yuqiao Li, Dezheng Li, Dehua He*, Recent research advances on catalysts for selective hydrogenation of ethyne, Catalysis Science & Technology, 13, 4045-4063, 2023.
lLan Ma, Huimin Liu*, Dehua He*, Recent Progress in Catalyst Development of the Hydrogenolysis of Biomass-Based Glycerol into Propanediols - A Review, Bioengineering, 10, 1264, 1-31, 2023.
lHuimin Liu, Yajin Li, Lan Ma, Jiaxiong Liu, Dehua He*, Photo-thermal conversion of CO2 and biomass-based glycerol into glycerol carbonate over Co3O4-ZnO p-n heterojunction catalysts, Fuel, 315, 123294, 2022 (DOI: 10.1016/j.fuel.2022.123294).
lYuqiao Li, Huimin Liu,* Ze Zheng, Zhu Fu, Dehua He*, Qijian Zhang*, Synthesis of Glycerol Carbonate via Alcoholysis of Urea with Glycerol: Current Status and Future Prospects, Industrial & Engineering Chemistry Research, 61, 5698-5711, 2022.
lHuimin Liu*, Xianguang Meng, Weiwei Yang, Guixia Zhao, Dehua He, Jinhua Ye*, Photo‐thermal CO2 reduction with methane on group VIII metals: In situ reduced WO3 support for enhanced catalytic activity, Chinese Journal of Catalysis, 42, 11, 1976-1982, 2021 (DOI: 10.1016/S1872-2067(21)63835-4).
lYajin Li, Huimin Liu,* Lan Ma, Jiaxiong Liu, Dehua He*, Transforming glycerol and CO2 into glycerol carbonate over La2O2CO3-ZnO catalyst — a case study of the photo-thermal synergism, Catal. Sci. Technol., 11, 1007-1013, 2021 (DOI: 10.1039/d0cy01821j).
lHuimin Liu*, Yajin Li, Dehua He*, Recent Progress of Catalyst Design for Carbon Dioxide Reforming of Methane to Syngas, Energy Technology, 8(8), 1900493, 2020 (DOI: 10.1002/ente.201900493).
lHuimin Liu, Li Wei, Fei Liu, Zengxia Pei, Jeffrey Shi, Zhoujun Wang*, Dehua He*, Yuan Chen*, Homogeneous, heterogeneous, and biological catalysts for electrochemical N2 reduction toward NH3 under ambient conditions, ACS Catal., 9, 5245-5267, 2019.
lJiaxiong Liu, Yajin Li, Huimin Liu*, Dehua He*, Photo-thermal Synergistically Catalytic Conversion of Glycerol and Carbon Dioxide to Glycerol Carbonate over Au/ZnWO4-ZnO Catalysts, Applied Catalysis B, 244, 836-843, 2019.
lHao Wu, Jiaxiong Liu, Huimin Liu*, Dehua He*, CO2 reforming of methane to syngas at high pressure over bi-component Ni-Co catalyst: The anti-carbon deposition and stability of catalyst, Fuel, 235, 868-877, 2019.
lJiaxiong Liu, Dehua He*, Transformation of CO2 with glycerol to glycerol carbonate by a novel ZnWO4-ZnO catalyst, Journal of CO2 Utilization, 26, 370-379, 2018.
lJiaxiong Liu, Yajin Li, Huimin Liu*, Dehua He*, Transformation of CO2 and glycerol to glycerol carbonate over CeO2-ZrO2 solid solution - effect of Zr doping, Biomass & Bioenergy, 118, 74-83, 2018.
lYajin Li, Jiaxiong Liu, Huimin Liu, Dehua He*, Catalytic synthesis of glycerol carbonate from biomass-based glycerol and dimethyl carbonate over Li-La2O3 catalysts, Applied Catalysis A, 564, 234-242, 2018.
lWeiwei Yang, Dehua He*, Role of poly(N-vinyl-2-pyrrolidone) in Ni dispersion for highly-dispersed Ni/SBA-15 catalyst and its catalytic performance in carbon dioxide reforming of methane, Applied Catalysis A, 524: 94-104, 2016
lWeiwei Yang, Huimin Liu, Yuming Li, Dehua He*, Interaction Mechanism of Ni(NO3)2·6H2O and P123 in Preparing Highly-Dispersed Ni/SBA-15 Catalytic Materials, Microporous and Mesoporous Materials, 228: 174-181, 2016
lWeiwei Yang, Huimin Liu, Yuming Li, Hao Wu, Dehua He*, CO2 reforming of methane to syngas over highly-stable Ni/SBA-15 catalysts prepared by P123-assisted method, International Journal of Hydrogen Energy, 41: 1513-1523, 2016
lWeiwei Yang, Huimin Liu, Yuming Li, Juan Zhang, Hao Wu, Dehua He*, Properties of yolk–shell structured Ni@SiO2 nanocatalyst and its catalytic performance in carbon dioxide reforming of methane to syngas, Catalysis Today, 259: 438-445, 2016
lHao Wu, Huimin Liu, Weiwei Yang, Dehua He*, Synergetic effect of Ni and Co in Ni-Co/SBA-15-CD catalysts and their catalytic performance in carbon dioxide reforming of methane to syngas, Catalysis Science & Technology, 14: 5631- 5646, 2016
lJiaxiong Liu, Yuming Li, Juan Zhang, Dehua He*, Glycerol carbonylation with CO2 to glycerol carbonate over CeO2 catalyst and the influence of CeO2 preparation methods and reaction parameters, Applied Catalysis A: 513: 9-18, 2016
lYuming Li, Huimin Liu, Lan Ma, Dehua He*, Influence of Pd precursors and Cl addition on performance of Pd-Re catalysts in glycerol hydrogenolysis to propanediols, Applied Catalysis A, 522: 13-20, 2016
lYuming Li, Huimin Liu, Lan Ma, Dehua He*, Synergistic effect between Pd and Re on Pd-Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis, RSC Advances, 45: 38680-38689, 2016
lJuan Zhang, Dehua He,* Synthesis of glycerol carbonate and monoacetin from glycerol and carbon dioxide over Cu catalysts: the role of supports, Journal of Chemical Technology and Biotechnology, 90: 1077-1085, 2015
lHuimin Liu, Yuming Li, Hao Wu, Jiaxiong Liu, Dehua He*, Effects of alpha- and gamma-cyclodextrin-modified impregnation method on physicochemical properties of Ni/SBA-15 and its catalytic performance in CO2 reforming of methane, Chinese Journal of Catalysis, 36: 283-289, 2015
lQinghui Cheng, Weiwei Yang, Zejun Li, Qiufeng Zhu, Taiwei Chu, Dehua He, Chao Fang, Adsorption of gaseous radioactive iodine by Ag/13X zeolite at high temperatures. Journal of Radioanalytical and Nuclear Chemistry, 303: 1883-1889, 2015
lYuming Li, Lan Ma, Huimin Liu, Dehua He*, Influence of HZSM5 on the Activity of Ru Catalysts and Product Selectivity During the Hydrogenolysis of Glycerol, Applied Catalysis A, 469: 45-51, 2014
lYuming Li, Huimin Liu, Lan Ma, Dehua He*, Glycerol Hydrogenolysis to Propanediols over Supported Pd-Re Catalysts, RSC Advances, 11: 5503-5512, 2014
lYuming Li, Lan Ma, Huimin Liu, Dehua He*, Influence of pretreatment on the catalytic performance of Ru/SBA-15 catalysts for glycerol hydrogenolysis, Chinese Journal of Catalysis, 35, 677-683, 2014.
lHuimin Liu, Hao Wu, Dehua He*, Methane Conversion to Syngas over Ni/Y2O3 Catalysts — Effects of Calcination Temperatures of Y2O3 on Physicochemical Properties and Catalytic Performance, Fuel Processing Technology, 119, 81-86, 2014.
lHuimin Liu, Yuming Li, Hao Wu, Weiwei Yang, Dehua He*, Effects of Nd, Ce and La Modification on the Catalytic Performance of Ni/SBA-15 Catalyst in CO2 Reforming of Methane, Chinese Journal of Catalysis, 35, 1520-1528, 2014.
lJuan Zhang, Dehua He*, Surface properties of Cu/La2O3 and its catalytic performance in the synthesis of glycerol carbonate and monoacetin from glycerol and carbon dioxide, Journal of Colloid and Interface Science, 419, 31-38, 2014.
lJuan Zhang, Dehua He*, Lanthanum-based mixed oxides for the synthesis of glycerol carbonate from glycerol and urea, Reaction Kinetics, Mechanisms and Catalysis, 113(2), 375-392, 2014.
lHuimin Liu, Yuming Li, Hao Wu, Takanori Miyake, Dehua He*, CO2 Reforming of Methane over Ni/SBA-15 Prepared with β-Cyclodextrin — Role of β-Cyclodextrin in Ni Dispersion and Performance, International Journal of Hydrogen Energy, 38, 15200-15209, 2013.
lHuimin Liu, Yuming Li, Hao Wu, Hiroya Takayama, Takanori Miyake, Dehua He*, Effects of Beta-cyclodextrin Modification on Properties of Ni/SBA-15 and Its Catalytic Performance in Carbon Dioxide Reforming of Methane, Catalysis Communications, 28, 168-173, 2012.
lHuimin Liu, Dehua He*, Recent Progress on Ni-Based Catalysts in Partial Oxidation of Methane to Syngas, Catalysis Survedys from Asia, 16, 53-61, 2012.
lRongjun Zhang, Huimin Liu, Dehua He*, Pure Monoclinic ZrO2 Prepared by Hydrothermal Method for Isosynthesis, Catalysis Communications, 26, 244-247, 2012.
lRongjun Zhang, Dehua He*, Effect of alcohol solvents treated ZrO(OH)2 hydrogel on properties of ZrO2 and its catalytic performance in isosynthesis, Journal of Natural Gas Chemistry, 21, 1-6, 2012.
lYingyi Pan, Deyun Ma, Huimin Liu, Hao Wu, Dehua He and Yingwei Li*, , Journal of Materials Chemistry, 22, 10834-10839, 2012.
lYinan Wu, Fengting Li*, Huimin Liu, Wei Zhu, Minmin Teng, Yin Jiang, Weina Li, Dan Xu, Dehua He, Phillip Hannam and Guangtao Li*, Electrospun fibrous mats as skeletons to produce free-standing MOF membranes, Journal of Materials Chemistry, 22, 16971-16978, 2012.
lBizhen Yuan, Deyun Ma, Xi Wang, Zhong Li, Yingwei Li*, Huimin Liu, Dehua He, A microporous, moisture-stable, and amine-functionalized metal-organic framework for highly selective separation of CO2 from CH4, Chemical. Communications, 48, 1135–1137, 2012.
lQiufeng Zhu, Rongjun Zhang, Dehua He*, Effect of CaO Modification on Performance of CuZnAlZr Catalyst in Synthesis of Higher Alcohols from Synthesis Gas, Acta Physico-Chimica Sinica (Chinese), 28, 1461-1466, 2012.
lHuimin Liu, Dehua He*, Properties of Ni/Y2O3 and Its Catalytic Performance in Methane Conversion to Syngas, International Journal of Hydrogen Energy, 36, 14447-14454, 2011.
lLan Ma, Yuming Li, Dehua He*, Glycerol Hydrogenolysis to Propanediols over Ru-Re/SiO2: Acidic Property of Catalyst and Role of Re Component, Chinese Journal of Catalysis, 32, 872-876, 2011
lWeixia Wang, Yingwei Li*, Rongjun Zhang, Dehua He, Hongli Liu, Liao, Shijun Liao, Metal-organic framework as a host for synthesis of nanoscale Co3O4 as an active catalyst for CO oxidation, Catalysis Communications, 12, 875-879, 2011.
lJinjin Li, Lan Ma, Dehua He*, Guangxing Li* Hydroformylation of 1-Octene over Amorphous Co-P-B Catalysts, Chemical Journal of Chinese Universities (Chinese), 32(12), 2844-2848, 2011.
lYingyi Pan, Bizhen Yuan , Yingwei Li*, Dehua He*, Multifunctional catalysis by Pd@MIL-101: one-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal-organic framework, Chemical Communications, 46, 2280-2282, 2010.
lHuimin Liu, Dehua He*, Physicochemical Properties of Ni/gamma-Al2O3-AlN and Effects of AlN on Catalytic Performance of Ni/gamma- Al2O3-AlN in Partial Oxidation of Methane, Journal of Physical Chemistry C, 114(32), 13716-13721, 2010.
lWei Zhou, Yuming Li, Dehua He*, Substrate influences on activity and stability of SBA-15–Pr-anchored Rh–P complex catalysts for olefin hydroformylation, Applied Catalysis A: General, 377, 114-120, 2010.
lLan Ma, Dehua He*, Influence of catalyst pretreatment on catalytic properties and performances of Ru–Re/SiO2 in glycerol hydrogenolysis to propanediols, Catalysis Today, 149, 148-156, 2010.
lYongge Bai, Dehua He*, Shaohui Ge, Huimin Liu, Jinyao Liu, Wei Huang, Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2 catalysts on synthesis of methanol via CO hydrogenation, Catalysis Today, 149, 111-116, 2010.
lYueqin Song, Huimin Liu, Dehua He*, Effects of Hydrothermal Conditions of ZrO2 on Catalyst Properties and Catalytic Performances of Ni/ZrO2 in the Partial Oxidation of Methane, Energy & Fuels, 24, 2817-2824, 2010.
lJunying Long, Lan Ma, Dehua He*, 1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts, Acta Physico-Chimica Sinica (Chinese), 26(10), 2719-2725, 2010.
lLan Ma, Dehua He*, Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru-Re Bimetallic Catalysts, Topics in Catalysis, 52, 834-844, 2009.
lLan Ma, Qingrong Peng, Dehua He*, Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene, Catalysis Letters, 130, 137-146, 2009.
lLan Ma, Dehua He*, Effect of Rhenium Component and Preparation Methods of ZrO2 Support on Catalytic Performance of Ru-Re/ZrO2 for Glycerol Hydrogenolysis, Chinese Journal of Catalysis, 30, 471-478, 2009.
lLan Ma, Dehua He*, Studies on the Hydrogenation of Glycerol to Propylene Glycol over Ru-based Catalysts, Industrial Catalysis (Chinese), 17(supplement), 206-208, 2009.
lWei Zhou, Dehua He*, A facile method for promoting activities of ordered mesoporous silica-anchored Rh-P complex catalysts in 1-octene hydroformylation, Green Chemistry, 11, 1146-1154, 2009.
lWei Zhou, Dehua He*, Anchoring RhCl(CO)(PPh3)2 to -PrPPh2 Modified MCM-41 as Effective Catalyst for 1-Octene Hydroformylation, Catalysis Letters, 127, 437-443, 2009.
lYueqin Song, Huimin Liu, Shuqiang Liu, Dehua He*, Partial Oxidation of Methane to Syngas over Ni/Al2O3 Catalysts Prepared by a Modified Sol-Gel Method, Energy & Fuels, 23, 1925-1930, 2009.
lShuqiang Liu, Yueqin Song, Dehua He*, Zhanping Li, Partial Oxidation of Methane to Syngas over Cr2O3 Catalysts, Chemical Journal of Chinese Universities (Chinese), 30, 106-112, 2009.
lYingwei Li, Dehua He*, Shaohui Ge, Rongjun Zhang, Qiming Zhu, Effects of CO2 on Synthesis of Isobutene and Isobutane from CO2/CO/H2 Reactant Mixtures over Zirconia-based Catalysts, Applied Catalysis B: Environmental, 80, 72-80, 2008.
lYueqin Song, Dehua He*, Boqing Xu, Effects of Preparation Methods of ZrO2 Support on Catalytic Performances of Ni/ZrO2 Catalysts in Methane Partial Oxidation to Syngas, Applied Catalysis A: General, 337,19-28, 2008.
lLan Ma, Dehua He*, Zhanping Li, Promoting effect of rhenium on catalytic performance of Ru catalysts in hydrogenolysis of glycerol to propanediol, Catalysis Communications, 9, 2489-2495, 2008.
lWei Zhou, Dehua He*, Lengthening alkyl spacers to increase SBA-15-anchored Rh-P complex activities in 1-octene hydroformylation, Chemical Communications, 44, 5839-5841, 2008.
lShaohui Ge, Dehua He*, Zhanping Li, A Mesoporous Ce0.5Zr0.5O2 Solid Solution Catalyst for CO Hydrogenation to iso-C4 Hydrocarbons, Catalysis Letters, 126, 193-199, 2008.
lZhihui Zhu, Dehua He*, CO Hydrogenation to iso-C4 Hydrocarbons over CeO2-TiO2 Catalysts, Fuel, 870, 2229–2235, 2008.
lQijian Zhang*, Dehua He, Qiming Zhu, Direct partial oxidation of methane to methanol: Reaction zones and role of catalyst location, Journal of Natural Gas Chemistry, 17(1), 24-28, 2008.
lDehua He*, Lan Ma, Jinyao Liu, Research progress on hydrogen production by reformings of hydrocarbons and alcohols, Petrochemical Technology (Chinese), 37(4), 315-322, 2008.
lYingwei Li, Dehua He*, Zhihui Zhu, Qiming Zhu, Properties of Sm2O3-ZrO2 Composite Oxides and Their Catalytic Performance in Isosynthesis, Applied Catalysis A: General, 319, 119-127, 2007.
lQingrong Peng, Dehua He*, Hydroformylation of mixed octenes over immobilized Co-Ph3PO/PDMS/SiO2 catalyst, Catalysis Letters, 115(1-2), 19-22, 2007.
lLei Shi, Guoli Dong, Dehua He*, Influence of preparation parameters on catalytic performance of samaria in isosynthesis, Catalysis Communications, 8(3), 359-365, 2007.
lXin Zhang*, Qing Ye, Boqing Xu, Dehua He, Oxidative dehydrogenation of ethane over Co-BaCO3 catalysts using CO2 as oxidant: effects of Co promoter, Catalysis Letters, 117, 140-145, 2007.
lLan Ma, Dehua He*, Research progress on catalysts for the hydrogenation of glycerol to propylene glycol, Industrial Catalysis (Chinese), 15(supplement), 64-66, 2007.
lLan Ma, Dehua He*, Qingrong Peng, Shaohui Ge, Studies on a novel Co Catalyst for Olefin Hydroformylation, Industrial Catalysis (Chinese), 15(supplement), 343-344, 2007.
lHongda Wu, Dehua He*, Studies on CuO/La2O3-ZrO2 catalysts for production of hydrogen by ethanol steam reforming, Petrochemical Technology (Chinese), 36(4), 334-339, 2007.
lXiaoqiang Yang, Guoli Dong, Dehua He*, Influence of Filling Inert Stuffing on Methane Partial Oxidation, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 31(4), 1-7, 2006.
lHongda Wu, Dehua He*, Hydrogen production by steam reforming of ethanol over CuO/La2O3-ZrO2, Petrochemical Technology (Chinese), 35(12), 1134-1139, 2006.
lXin Zhang, Dehua He*, Qijian Zhang, Boqing Xu, Qiming Zhu, Comparative studies on direct conversion of methane to methanol/ formaldehyde over La–Co–O and ZrO2 supported molybdenum oxide catalysts, Topics in Catalysis, 32(3-4), 215-223, 2005.
lHui Wang, Guoli Dong, Dehua He*, Steam reforming of ethanol over Cu/ZrO_2 catalysts Ⅱ Influences of reaction conditions, Journal of Fuel Chemistry and Technology (Chinese), 33(5), 607-611, 2005.
lHui Wang, Guoli Dong, Dehua He*, Steam reforming of ethanol over Cu/ZrO2 catalysts Ⅰ Effects of the preparation parameters of the catalysts, Journal of Fuel Chemistry and Technology (Chinese), 33(3), 344-350, 2005.
lLan Wei, Dehua He*, Studies of Hydroformylation of Higher Olefins, Progress in Chemistry (Chinese), 17 (2), 217-224, 2005.
lJie Hu, Dehua He*, Influences of Ni/ZrO2 Catalyst Preparation Conditions on Steam Reforming of Methane, Journal of Zhengzhou University (Natural Science Edition) (Chinese), 37(3), 64, 2005.
lXiaoqiang Yang, Guoli Dong, Dehua He*, Study on methane conversion over WOx/Co-Fe-Mo-O catalysts, Petrochemical Technology (Chinese), 34(12), 1134-1139, 2005.
lYingwei Li, Dehua He*, Qiming Zhu, Xin Zhang, Boqing Xu, Effects of redox and acid-base properties on the isosynthesis over ZrO2 based catalysts, Journal of Catalysis, 221(2), 584-593, 2004.
lXin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Methanol from oxidation of methane over MoOx/ La-Co-oxide catalysts, Study in Surface Science and Catalysis, 147, 541-546, 2004.
lXin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Characterization and catalytic performance of Zr-Mo-oxide catalysts for selective oxidation of methane to formaldehyde, Composite Interfaces, 11 (2), 153, 2004.
lJie Hu, Dehua He*, Yingwei Li, Xin Zhang, Hui Wang, Studies on Steam Reforming of Methane over Ni/ZrO2 Catalyst, Journal of Fuel Chemistry and Technology (Chinese), 32(1), 98, 2004.
lLan Wei, Dehua He*, Guoli Dong, Effect of Reaction Conditions on Hydroformylation of Mixed Octenes Catalyzed by Co Catalyst, Petrochemical Technology (Chinese), 33(6), 512, 2004.
lXin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Selective oxidation of methane to formaldehyde over Mo/ZrO2 catalysts, Applied Catalysis A: General, 249(1), 107, 2003.
lYingwei Li, Dehua He*, Qijian Zhang, Qiming Zhu, Influence of reactor materials on i-C4 synthesis from CO hydrogenation over ZrO2 based catalysts, Fuel Processing Technology, 83(1-3), 39-48, 2003.
lQijian Zhang, Dehua He*, Xin Zhang, Qiming Zhu, Shuiliang Yao, Direct Partial Oxidation of Methane to Methanol in a Specially Designed Reactor, ACS Sym. Ser. 852: Utilization of Greenhouse Gases, pp280-290, American Chemical Society Press, Washington DC, 2003.
lXin Zhang*, Dehua He*, Qijian Zhang, B. Xu, Q. Zhu, Selective oxidation of methane to methanol using molecular oxygen on MoOx/(LaCoO3+Co3O4) catalysts, Chinese Chemical Letters, 14 (10), 1066-1069, 2003.
lQijian Zhang, Dehua He*, Qiming Zhu, Recent Progress in Direct Partial Oxidation of Methane to Methanol, Journal of Natural Gas Chemistry, 12(2), 81-89, 2003.
lYuhe Wang, Dehua He, Boqing Xu*，Studies of producing acetic acid by carbonylation of methanol, Progress in Chemistry (Chinese), 15 (3), 215-221, 2003
lXin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Selective Oxidation of Methane to Formaldehyde over Mo/ZrO2 Catalysts, Chinese Journal of Catalysis, 24(1), 22-26, 2003.
lXin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Studies on Selective Oxidation of Methane to Methanol over Mo/La-Co-O Catalyst, Chinese Journal of Catalysis, 24(4), 305-311, 2003.
lDehua He*, Dongcheng Pang, Lan Wei, Zhigang Tang, Jinyao Liu, Qiming Zhu, Influences of Ammonium Salt Additives on Hydroformylation of Higher Olefins Catalyzed by Rhodium, Petrochemical Technology (Chinese), 32(2), 93-95, 2003.
lXin Zhang*, Dehua He, Qijian Zhang, Qiming Zhu, Studies on Gas-Phase Homogeneous Selective Oxidation of Methane to Methanol, Petrochemical Technology (Chinese), 32(3), 195-199, 2003.
lJie Hu, Dehua He*, New progress in study of methane direct conversion and syngas technology, Natural Gas Chemical Industry (C1 Chemistry and Technology) (Chinese), 28(2), 46-51, 2003.
lQijian Zhang, Dehua He*, Jinlu Li, Boqing Xu, Yu Liang, Qiming Zhu, Comparatively high yield methanol production from gas phase partial oxidation of methane, Applied Catalysis A: General, 224 (1-2), 201, 2002.
lQijian Zhang, Dehua He*, Zhansheng Han, Boqing Xu, Qiming Zhu, Controlled Partial Oxidation of Methane to Methanol /formaldehyde over Mo-V-Cr-Bi-Si Oxide catalysts, Fuel, 81, 1599, 2002.
lYingwei Li, Dehua He*, Yubin Yuan, Zhenxing. Cheng, Qiming Zhu, Influence of Acidic and Basic Properties of ZrO2 Based Catalysts on Isosynthesis, Fuel, 81, 1611, 2002.
lYingwei Li, Dehua He*, Yubin Yuan, Zhenxing Cheng, Qiming Zhu, Synthesis of isobutene from CO hydrogenation over nanosized zirconium dioxide-based catalysts, Chinese Journal of Catalysis, 23(2), 185-190, 2002.
lDehua He*, Dongcheng Pang, Yu Chen, Lan Wei, Tong-en Wang, Jinyao Liu, Yan Liu, Qiming Zhu, Hydroformylation of C8 Olefins Catalyzed by Rhodium-Inorganic Ammonium Salt Systems, Catalysis Communications, 3 (9), 429-433, 2002.
lXin Zhang*, Dehua He*, Qijian Zhang, Qing Ye, Qiming Zhu, Partial Oxidation of Methane to Formaldehyde over Superfine Mo/ZrO2 catalysts, Journal of Natural Gas Chemistry, 11(1-2), 15-17, 2002.
lTetsuya Takemoto, Dehua He, Yonghong Teng, Kenji Tabata*, Eiji Suzuki, Enhancement of Methanol Selectivity in the Products of Direct Selective Oxidation of Methane in CH4-O2-NO with Cu-ZnO/SiO2, Applied Catalysis A: General, 225, 177, 2002.
lTetsuya Takemoto, Dehua He, Yonghong Teng, Kenji Tabata*, Eiji Suzuki, The Optimization of Methanol Yield in the Products of Direct Selective Oxidation of Methane in CH4-O2-NO with Cu-ZnO/Al2O3, Journal of Molecular Catalysis A: Chemical, 179, 279, 2002.
lYingwei Li, Dehua He*, Zhenxing Cheng, Caili Su, JinluLi, Qiming Zhu, Effect of calcium salts on isoynthesis over ZrO2 catalysts, J. Molecular Catalysis A: Chemical, 175(1-2), 267, 2001.
lDehua He*, Dongcheng Pang, Yu Chen, Tong-en Wang, Yan Liu, Jinyao Liu, Qiming Zhu, Hydroformylation of Mixture of Isomeric Octenes to C9-Aldehydes Catalyzed by Rh-Phosphine Oxide Complexes, J. Molecular Catalysis A: Chemical, 174(1-2), 21, 2001.
lYingwei Li, Dehua He*, Yubin Yuan, Zhenxing Cheng, Qiming Zhu, Selective Formation of Isobutene from CO Hydrogenation over Zirconium Dioxide Based Catalysts, Energy and Fuels, 15, 1434, 2001.
lJinyao Liu*, Jiangliu Shi, Dehua He, Qijian Zhang, Xiaohui Wu, Yu Liang, Qiming Zhu, Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction, Applied Catalysis A: General, 218, 113, 2001.
lDehua He, Jinyao Liu*, Yan Liu, Tong-en Wang, Dongcheng Pang, Yu Chen, Yu Liang, Qiming Zhu, Effects of Ammonium Salts as Additives in Rh-Ph3PO Catalytic System on Hydroformylation of Mixed Octenes, Catalysis Letters, 73(2-4), 221, 2001.
lT. Takemoto, Dehua He, Y. Teng, A. Nakayama, K. Tabata*, E. Suzuki, Enhancement of Methanol Selectivity in the Products of Direct Selective Oxidation of Methane in CH4-O2-NO with Cu-ZnO/Al2O3, Journal of Catalysis, 198(1), 109, 2001.
lYingwei Li, Dehua He*, Zhenxing Cheng, Caili Su, Junrong Li, Qiming Zhu, Effect of calcium salts on selective formation of i-C4 from CO hydrogenation over ZrO2 catalysts, Natural Gas Chemical Industry (C1 Chemistry and Technology) (Chinese), 26(4), 9, 2001.
lWeiguo Huang*, Dehua He, Jinyao Liu, Qiming Zhu, Catalytic Condensation of Formaldehyde and Methyl Formate over 12-Tungstosilicic Compounds, Applied Catalysis A: General, 199, 93, 2000.
lCaili Su, Dehua He*, Junrong Li, Boqing Xu, Zhenxing Cheng, Qiming Zhu, Influences of preparation parameters on the structural and catalytic performance of Zirconia in isosynthesis, Journal of Molecular Catalysis A: Chemical, 153, 139, 2000.
lCaili Su*, Junrong Li, Dehua He, Zhenxing Cheng, Qiming Zhu, Synthesis of isobutene from Syn-gas over Nanosize zirconia Catalysts, Applied Catalysis A: General, 202, 81, 2000.
lCaili Su, Dehua He*, Junrong Li, Boqing Xu, Zhenxing Cheng, Qiming Zhu, Relationship between Formation of DEM, CH3OH and i-C4H8 in Iso-synthesis, Study in Surface Science and Catalysis, 130, 3735, 2000.
lDehua He*, Qiming Zhu, Noriko Wakasa, Takamasa Fuchikami, Preparation of ω-Hydroxy Carboxylic Esters from Hydrogenation of α,ω-Dicarboxylic Acid Monoesters over Rh Based Bicomponent Catalysts, Petrochemical Technology (Chinese), 29(1), 26, 2000.
lYe Liu, Dehua He*, Chunbo Li, Tongen Wang, Jinyao Liu, Qiming Zhu, Syntheses of Diphosphine and Diphosphine (mono-, di-) Oxides, and Hydroformylation of Mixed Octenes Based on Rh-P Catalytic Systems, Journal of Molecular Catalysis (China), 14(5), 337, 2000.
lYe Liu, Dehua He*, Chongwei Liu, Tongen Wang, Jinyao Liu, Qiming Zhu, Hydroformylation of Octenes over Rh/Ph3PO Catalytic System and its In-situ Infrared Characterization, Journal of Molecular Catalysis (China), 14(3), 227, 2000.
lTongen Wang, Dehua He*, Ye Liu, Jinyao Liu, Dongcheng Pang, Yu Chen, Qiming Zhu, Effect of the reaction conditions on the hydroformylation of mixed octenes in the Rh-Ph3PO catalysis system, Natural Gas Chemical Industry (C1 Chemistry and Technology) (Chinese), 25(5), 14, 2000.
lYu Chen, Dehua He*, Jinyao Liu, Ye Liu, Tongen Wang, Qiming Zhu, Hydroformylation of 1-octene over Rh/P catalysts, Natural Gas Chemical Industry (C1 Chemistry and Technology) (Chinese), 25(3), 15, 2000.
lTongen Wang, Dehua He*, Ye Liu, Jinyao Liu, Hongzhen Lin, Yu Liang, Chongwei Liu, Qiming Zhu, Studies on Hydroformylation of Mixed C-8 Olefins, Coal Chemical Industry (Chinese), 7(3), 20, 2000.
lDehua He*, Weiguo Huang, Jinyao Liu, Qiming Zhu, The activity of H4SiW12O40 for the coupling of formaldehyde and methyl formate to methyl glycolate and methyl methoxy acetate, Journal of Molecular Catalysis A: Chemical, 145 (1-2), 335 (1999).
lDehua He*, Weiguo Huang, Jinyao Liu, Qiming Zhu, Condensation of formaldehyde and methyl formate to methyl glycolate and methyl methoxy acetate using heteropolyacids and their salts, Catalysis Today, 51 (1), 127 (1999).
lChongwei Liu, Yingwei Li, Dehua He*, Jinyao Liu, Qiming Zhu, In-situ infrared study on activation of several rhodium complexes in 1-octene, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 24(4), 8, 1999.
lDehua He*, Weiguo Huang, Jinyao Liu, Mingxing Zhou, Qiming Zhu, Studies on synthesis of methyl glycolate and methyl methoxy acetate from the coupling of formaldehyde and methyl formate, The Korea Journal of Chemical Engineering (English), 15(5), 556, 1998.
lQiang Xu*, Dehua He, Masahiro Fujiwara, Mutsuo Tanaka, Yoshie Souma, Hiroshi Yamanaka, Hydrogenation of carbon-dioxide over Fe-Cu-Na/zeolite composite catalysts -- Na migration via solid - solid reaction and its effects on the catalytic activity, J. Molecular Catalysis A: Chemical, 136,161, 1998.
lQiang Xu*, Dehua He, Masahiro Fujiwara, Mutsuo Tanaka, Yasuyuki. Matsumura, Yoshie Souma, Hisanori. Ando, Hiroshi Yamanaka, Hydrogenation of carbon-dioxide over Fe-Cu-Na/zeolite composite catalysts, Studies in Surface Science and Catalysis, 114, 423, 1998.
lCaili Su, Junrong Li, Dehua He, Zhenxing Cheng, Qiming Zhu*, Synthesis of iso-C4 and dimethyl ether from syn-gas over superfine zirconia catalysts, Advances of Alcohol Fuels in The World, Edited by Zhu QM, Tsinghua University Press, pp55-60, 1998.
lDehua He*, Qiming Zhu, Noriko Wakasa, Takamasa Fuchikami, Synthesis of w-hydroxy carboxylic esters from the hydrogenation of a,w-dicarboxylic acid monoesters over Ru based bicomponent catalysts, Journal of Molecular Catalysis (China), 12(3), 175, 1998.
lCaili Su*, Dehua He, Yunfan Zou, Weixiong Pan, Qiming Zhu, Effect of different zeolite supports on the product distribution of CO hydrogenation, Chinese Journal of Catalysis, 19(6), 571, 1998.
lCaili Su*, Yunfan Zhou, Weixong Pan, Dehua He, Qiming Zhu, Synthesis of mesoporous molecular sieves and their application as supports for catalysts in F-T synthesis, Journal of Fuel Chemistry and Technology (Chinese), 26(4), 297, 1998.
lDehua He*, Qiming Zhu, Qiang Xu, Masahiro Fujiwara, Yoshie Souma, Hydrogenation of CO2 over Cu-Fe-Na/zeolite composite catalysts, Journal of Fuel Chemistry and Technology (Chinese), 26(3), 197, 1998.
lWeiguo Huang, Dehua He*, Jinyao Liu, Qiming Zhu, Coupling reaction of formaldehyde and methyl formate - II Catalysis by salts of heteropolyacid, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 23(4), 4, 1998.
lWeiguo Huang, Dehua He*, Jinyao Liu, Shi Li, Qiming Zhu, Coupling reaction of formaldehyde and methyl formate - I Catalysis by heteropolyacids, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 23(3), 6, 1998.
lQ. Xu*, Dehua He, Masahiro Fujiwara, Yoshie Souma, Improved activity of Fe-Cu catalysts by physical mixing with zeolite for the hydrogenation of carbon dioxide, J. Molecular Catalysis A:Chemical, 120, L23,1997.
lDehua He*, Qiming Zhu, Noriko Wakasa, Takamasa Fuchikami, Studies on Synthesis of γ--Butyrolactone by the Hydrogenation of Maleic Anhydride and Its Derivatives — The Catalytic Properties of Ruthenium Complex Catalysts and the Effect of Additives, Petrochemical Technology (Chinese), 26(7), 425-429, 1997.
lDehua He*, Qiming Zhu, Qiang Xu, Masahiro Fujiwara, Yoshie Souma, Effects of Na remaining in Cu-Fe mixed oxide catalysts on CO2 hydrogenation, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 22(6) , 1-5, 1997
lWeiguo Huang, Dehua He*, Jinyao Liu, Qiming Zhu, Ethylene glycol synthesis ways through non-oil route, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 22(5) , 35, 1997.
lDehua He*, Weiguo Huang, Jinyao Liu, Mingxing Zhou, Qiming Zhu, Studies on synthesis of methyl glycolate via the coupling of methyl formate with formaldehyde ¾ catalytic performance of acid catalysts and the effect of reaction conditions, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 22(4) , 1-5, 1997.
lDehua He*, Qiming Zhu, Noriko Wakasa, Takamasa Fuchikami, Studies on synthesis of g-butyrolactone via the hydrogenation of maleic anhydride and its derivatives ¾ the catalytic properties of supported palladium catalysts and the effect of zeolits, Natural Gas Chemical Industry(C1 Chemistry and Technology)(Chinese), 22(1) , 32, 1997.
lDehua He*, Xuanwen Li, Weimin Yuan, Ping Wei, Study on Catalysts for the Synthesis of γ-Butyrolactone by Hydrogenation of Maleic Anhydride, Industrial Catalysis (Chinese), 4, 21-25, 1997.
lDehua He, Noriko Wakasa, Takamasa Fuchikami*, Hydrogenation of carboxylic acids using bimetallic catalysts consisting of group 8 to 10 and group 6 or 7 metals, Tetrahedron Letter, 36(7), 1059-1062, 1995.
➢Selected Authorised patents:
Patent Title |
Country |
Patent No. |
Authorized Date |
Zirconia catalyst and promoters for isobutene preparation from syngas. |
China Patent |
ZL 99121713.6 |
2003.05.21 |
A process for preparation of aldehydes from olefins, CO and hydrogen. |
China Patent |
ZL 00128279.4 |
2003.10.8 |
Mo-Co-La-oxide catalysts and their preparation methods for formaldehyde synthesis from methane oxidation. |
China Patent |
ZL02125911.9 |
2003.12.17 |
Mo-Zr-oxide catalysts and their preparation methods for formaldehyde synthesis from methane oxidation. |
China Patent |
ZL02125912.7 |
2003.12.17 |
A process and a specially designed reactor for methanol synthesis from gas phase oxidation of nature gas. |
China Patent |
ZL 01120438.9 |
2004.02.11 |
A process for preparation of iso-butene and iso-butane |
China Patent |
ZL200310115541.0 |
2005.11.09 |
A process for preparation of iso-octane |
China Patent |
ZL200410009950.7
|
2006.06.07 |
Process for preparation of iso-nonyl aldehydes from mixed octenes and syngas |
China Patent |
ZL200410062259.5 |
2007.03.07 |
Preparation and application of Sm2O3 catalyst |
China Patent |
ZL200410012736.8 |
2007.08.22 |
A process for preparation of propanediols from hydrogenolysis of glycerol |
China Patent |
ZL200810103814.2 |
2010.04.11 |
A process for preparation of aldehydes from olefins and syngas |
China Patent |
ZL 200810089634.3 |
2010.09.29 |
A method for the preparation of H2 and CO syngas by partial oxidation of methane |
China Patent |
ZL 200910088176.6 |
2011.06.29 |
A preparation method of Ni - based Catalyst for Partial Oxidation of Methane to Syngas |
China Patent |
ZL200910236532.4 |
2011.09.14 |
A preparation method of zirconia catalysts for preparing C2 - C4 olefin from CO hydrogenation |
China Patent |
ZL 201010205015.3 |
2012.05.16 |
A preparation method of catalysts for preparing mixed alcohols from synthesis gas |
China Patent |
ZL 201010523366.9 |
2012.05.16 |
A preparation method of catalysts for carbon dioxide reforming of methaneto syngas |
China Patent |
ZL201210156122.0 |
2014.07.23 |
A process for preparation of glycerol carbonate from carbon dioxide and glycerol |
China Patent |
ZL201810035744.5 |
2020.12.08 |
A process for preparation of glycerol carbonate from glycerol and CO2 |
China Patent |
ZL201811217180.3 |
2021.03.05 |
