华瑞茂 博士、教授

联系方式:清华大学化学系 北京 100084

Tel.: +86-10-62792596; Fax: +86-10-62771149

E-mail:ruimao@mail.tsinghua.edu.cn

教育背景

1992-1996 Ph. D. 东京工业大学 (日本)

1986-1989 M. Sc. 中国科学院大连化学物理研究所

1982-1986 B. Sc. 福建师范大学化学系

工作履历

1989-1992 中国科学院大连化学物理研究所 助理研究员

1996-2002 Japan Science and Technology Corporation (JSP), Research Fellow

2002-现在 清华大学化学系 教授

学术兼职

目前是国际学术杂志Current Organic Synthesis、Current Catalysis、Mini-Reviews in Organic Chemistry、Journal of Chemistry and Applications编委、Reports in Organic Chemistry名誉编委;国内《精细化工》、《液晶与显示》杂志编委;中国化学会催化学会均相催化专业委员会委员 (2011-)。曾经是国际学术杂志Catalysis Communications编委、中国区副编辑 (2005-2012)。

研究领域

炔烃化学、有机材料化学

学术成果

研究团队主要从事:(1) 基于炔烃为原料的原子经济性或高原子利用率有机合成方法学研究;(2) 液晶、OLED等显示用有机材料分子的设计与合成应用基础研究。建立了一系列高效、高选择性构建具有生物活性、特殊光电性质的官能团化有机分子骨架的新反应和新方法。发表SCI学术论文100多篇,被引用1600余次,h因子29;授权国内、外发明专利122项,在申请发明专利54项。

近年发表论文

1. Liyao Zheng, Yunhui Bin, Yunpeng Wang, Ruimao Hua*

Synthesis of Natural Product-like Polyheterocycles via One-Pot Cascade Oximation, C-H Activation and Alkyne Annulation.

The Journal of Organic Chemistry2016,81, 8911-8919

2. Biao Guo, Liyao Zheng, Lei Zhang, Ruimao Hua*

Synthesis of Benzofulvene Derivatives from Diarylacetylenes via Pd(II)-Catalyzed Alkyne-Directed C(sp2)-H Bond Activation.

The Journal of Organic Chemistry2015,80, 8430-8434

3. Biao Guo, Yiming Zhou, Lei Zhang, Ruimao Hua*

Bronsted Acid-Promoted One-Pot Synthesis of Chrysene Derivatives via Isochromenylium Intermediate Formedin Situ.

The Journal of Organic Chemistry2015,80, 7635-7641

4. Lei Zhang, Liyao Zheng, Biao Guo, Ruimao Hua*

One-Pot Synthesis of Multisubstituted 2-Aminoquinolines from Annulation of 1-Aryl Tetrazoles with Internal Alkynes via Double C-H Activation and Denitrogenation.

The Journal of Organic Chemistry2014,79, 11541-11548

5. Biao Guo, Liyao Zheng, Lichen Yang, Ruimao Hua*

Synthesis of Chrysene Derivatives via Copper-Catalyzed One-Pot Dimerization of 2-Alkynyl-1-acetylbenzenes.

The Journal of Organic Chemistry2014,79, 4352-4357

6. Liyao Zheng, Ruimao Hua*

Modular Assembly of Ring-Fused and π-Extended Phenanthroimidazoles via C-H Activation and Alkyne Annulation.

The Journal of Organic Chemistry2014,79, 3930-3936

7. Liyao Zheng, Jia Ju, Yunhui Bin, Ruimao Hua*

Synthesis of Isoquinolines and Heterocycle-Fused Pyridines via Three-Component Cascade Reaction of Aryl Ketones, Hydroxylamine, and Alkynes.

The Journal of Organic Chemistry2012,77, 5794-5800

8. Jie Li, Ruimao Hua*, Tao Liu

Highly Chemo- and Stereoselective Palladium-Catalyzed Transfer Semihydrogenation of Internal Alkynes Affording cis-Alkenes.

The Journal of Organic Chemistry2010,75, 2966-2970

9. Ming Li, Ruimao Hua*

Ru3(CO)12-Catalyzed Reactions of Catechols with Alkynes: An Atom-Economic Process for the Synthesis of 2,2-Disubstituted 1,3-Benzodioxoles from the Double Addition of the O-H Bond Across a Triple Bond.

The Journal of Organic Chemistry2008,73, 8658-8660

10. Hanxiang Zeng, Ruimao Hua*

Palladium-Catalyzed Hydrophenylation of Alkyne with Sodium Tetraphenylborate under Mild Conditions.

The Journal of Organic Chemistry2008,73, 558-562

学术论文章节编著

(1) 著者:“Recent Advances in Organocatalysis”一书(2016年InTech出版社出版;主编:Iyad Karame & Hassan Srour)第5章:“Organocatalytic Transformation of Carbon Dioxide”

(2) 著者:“Copper-Mediated Cross-Coupling Reactions”一书(2013年Wiley出版社出版;主编:Gwilherm Evano & Nicolas Blanchard)第12章:“Copper-Catalyzed Alkynylation and Alkenylation Reaction of Alkynyl Derivatives: New Access to Diynes and Enynes”

(3) 客座编辑:Current Organic Chemistry, 2011年第15卷第5期特刊: Recent Progress in the Synthesis and Applications of Cyclic Compounds

(4) 著者:2008年化学工业出版社出版的《现代有机反应》丛书,第五卷“金属催化反应”中的“Sonogashira Reaction”和“Ullmann Reaction”两章。