
贺德华(HE Dehua) 教授,博士生导师
通讯地址:北京海淀清华大学 化学系 (邮编100084)
电子邮件:hedeh@mail.tsinghua.edu.cn
目前讲授的课程:多相催化动力学
教育背景
学士,华东理工大学(石油化工),1982.1
硕士,日本冈山大学(合成化学),1987.3
博士,日本东京工业大学(化学环境工程),1990.3
工作履历
1991-1994,日本相模中央化学研究所,研究人员
1995-现在,清华大学化学系,教师
1999-2000,日本地球环境产业技术研究所,客座研究人员
2003-2004,美国弗吉尼亚大学,访问学者
研究领域
多相、均相催化(主要研究一碳化学、燃料化学、生物质转化、精细化学品合成以及环境治理中的催化剂和催化反应工艺。)
研究概况
目前的研究课题:
● 丙三醇和二氧化碳直接转化制丙三醇碳酸酯催化剂的研发
● 从二氧化碳和甲醇合成碳酸二甲酯催化剂的研究
● 二氧化碳重整甲烷制合成气Ni基催化剂的研究
过去的研究课题:
● 生物质来源丙三醇催化氢解制丙二醇催化剂的研究
● 甲烷部分氧化制合成气(以及制甲醇/甲醛)催化剂的研究
● CO/H2异构合成制异构碳四烃催化剂与催化工艺的研究
● 合成气制低碳醇催化剂与催化工艺的研究
● 混合辛烯氢甲酰化制C9醛催化剂与催化工艺的研究
● Rh-P均相催化剂固载化新方法及氢甲酰化的研究
● 用于烯烃氢甲酰化的无定形Co-B催化剂的研究
研究基金(负责):
● 国家自然科学基金(批准号:21573120, 21073104, 20973098, 20673064, 20410202074, 20373031)
● 国家重点基础研究发展规划(973计划,2011CB201400) (第五课题,批准号:2011CB201405)
● 国家高技术研究发展计划(863计划,洁净煤技术专题) (批准号:2007AA05Z332)
● 高等学校博士学科点专项科研基金(批准号:20973098, 2007003108)
● 国际合作项目(中韩)
学术成果
部分代表论文:
Weiwei Yang, Dehua He*, Role of poly(N-vinyl-2-pyrrolidone) in Ni dispersion for highly-dispersed Ni/SBA-15 catalyst and its catalytic performance in carbon dioxide reforming of methane,Applied Catalysis A, 524: 94-104, 2016
Weiwei Yang, Huimin Liu, Yuming Li, Dehua He*,Interaction Mechanism of Ni(NO3)2·6H2O and P123 inPreparing Highly-Dispersed Ni/SBA-15 CatalyticMaterials,Microporous and Mesoporous Materials, 228: 174-181, 2016
Weiwei Yang, Huimin Liu, Yuming Li, Hao Wu, Dehua He*,CO2reforming of methane to syngas over highly-stable Ni/SBA-15 catalysts prepared by P123-assisted method,International Journal of Hydrogen Energy, 41: 1513-1523, 2016
Weiwei Yang, Huimin Liu, Yuming Li, Juan Zhang, Hao Wu, Dehua He*, Properties of yolk–shell structuredNi@SiO2nanocatalyst and its catalytic performance in carbon dioxide reforming of methane to syngas,Catalysis Today, 259: 438-445, 2016
Hao Wu, Huimin Liu, Weiwei Yang, Dehua He*, Synergetic effect of Ni and Co in Ni-Co/SBA-15-CD catalysts and their catalytic performance in carbon dioxide reforming of methane to syngas,Catalysis Science & Technology, 14: 5631- 5646, 2016
Jiaxiong Liu, Yuming Li, Juan Zhang, Dehua He*,Glycerol carbonylation with CO2to glycerol carbonate over CeO2catalyst and the influence of CeO2preparation methods and reaction parameters,Applied Catalysis A: 513: 9-18, 2016
Yuming Li, Huimin Liu, Lan Ma, Dehua He*,Influence of Pd precursors and Cl addition on performance of Pd-Re catalysts in glycerol hydrogenolysis to propanediols,Applied Catalysis A, 522: 13-20, 2016
Yuming Li, Huimin Liu, Lan Ma, Dehua He*,Synergistic effect between Pd and Re on Pd-Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis,RSC Advances, 45: 38680-38689, 2016
Juan Zhang, Dehua He,* Synthesis of glycerol carbonate and monoacetin from glycerol and carbon dioxide over Cu catalysts: the role of supports,Journal of Chemical Technology and Biotechnology, 90: 1077-1085, 2015
Huimin Liu, Yuming Li, Hao Wu, Jiaxiong Liu, Dehua He*, Effects of alpha- and gamma-cyclodextrin-modified impregnation method on physicochemical properties of Ni/SBA-15 and its catalytic performance in CO2reforming of methane,Chinese Journal of Catalysis, 36: 283-289, 2015
Qinghui Cheng, Weiwei Yang, Zejun Li, Qiufeng Zhu, Taiwei Chu, Dehua He, Chao Fang,Adsorption of gaseous radioactive iodine by Ag/13X zeolite at high temperatures.Journal of Radioanalytical and Nuclear Chemistry, 303: 1883-1889, 2015
Yuming Li, Lan Ma, Huimin Liu, Dehua He*, Influence of HZSM5 on the Activity of Ru Catalysts and Product Selectivity During the Hydrogenolysis of Glycerol,Applied Catalysis A, 469: 45-51, 2014
Yuming Li, Huimin Liu, Lan Ma, Dehua He*, Glycerol Hydrogenolysis to Propanediols over Supported Pd-Re,Catalysts, RSC Advances, 11: 5503-5512, 2014
Huimin Liu, Hao Wu, Dehua He*,Methane Conversion to Syngas over Ni/Y2O3Catalysts—Effects of Calcination Temperatures of Y2O3on Physicochemical Properties and Catalytic Performance,Fuel Processing Technology, 119: 81-86, 2014
Juan Zhang, Dehua He*, Surface properties of Cu/La2O3and its catalytic performance in the synthesis of glycerol carbonate and monoacetin from glycerol and carbon dioxide,Journal of Colloid and Interface Science, 419: 31-38, 2014
Juan Zhang, Dehua He*,Lanthanum-based mixed oxides for the synthesis of glycerol carbonate from glycerol and urea,Reaction Kinetics, Mechanisms and Catalysis, DOI: 10.1007/s11144-014-0739-6, 2014
Yuming Li, Lan Ma, Huimin Liu, Dehua He*, Influence of pretreatment on the catalytic performance of Ru/SBA-15 catalysts for glycerol hydrogenolysis,Chinese Journal of Catalysis, 35: 677-683, 2014
Huimin Liu, Yuming Li, Wwiwei Yang, Hao Wu, Dehua He*, Effects of Nd, Ce and La Modification on the Catalytic Performance of Ni/SBA-15 Catalyst in CO2Reforming of Methane,Chinese Journal of Catalysis, 35: 1520-1528, 2014
Huimin Liu, Yuming Li, Hao Wu, Takanori Miyake, Dehua He*, CO2Reforming of Methane over Ni/SBA-15 Prepared with β-Cyclodextrin — Role of β-Cyclodextrin in Ni Dispersion and Performance,International Journal of Hydrogen Energy, 38:15200-15209, 2013
Huimin Liu, Yuming Li, Hao Wu, Hiroya Takayama, Takanori Miyake, Dehua He*, Effects of Beta-cyclodextrin Modification on Properties of Ni/SBA-15 and Its Catalytic Performance in Carbon Dioxide Reforming of Methane,Catalysis Communications, 28: 168-173, 2012
Huimin Liu, Dehua He*,Recent Progress on Ni-Based Catalysts in Partial Oxidation of Methane to Syngas,Catalysis Survedys from Asia, 16:53-61, 2012
Rongjun Zhang, Huimin Liu, Dehua He*, Pure Monoclinic ZrO2 Prepared by Hydrothermal Method for Isosynthesis,Catalysis Communications, 26, 244–247, 2012
Qiufeng Zhu, Rongjun Zhang, Dehua He*, Effect of CaO Modification on Performance of CuZnAlZr Catalyst in Synthesis of Higher Alcohols from Synthesis Gas,ACTA PHYSICO-CHIMICA SINICA, 28:1461-1466, 2012
Rongjun Zhang, Dehua He*, Effect of alcohol solvents treated ZrO(OH)2hydrogel on properties of ZrO2 and its catalytic performance in isosynthesis,Journal of Natural Gas Chemistry, 21:1-6, 2012
Yingyi Pan, Deyun Ma, Huimin Liu,Hao Wu, Dehua He and Yingwei Li,Journal of Materials Chemistry,22, 10834-10839, 2012
Yinan Wu, Fengting Li, Huimin Liu,Wei Zhu, Minmin Teng, Yin Jiang, Weina Li, Dan Xu, Dehua He, Phillip Hannam and Guangtao Li,Journal of Materials Chemistry,22, 16971-16978, 2012
Bizhen Yuan, Deyun Ma, Xi Wang, Zhong Li, Yingwei Li, Huimin Liu, Dehua He, A microporous, moisture-stable, and amine-functionalized metal-organic framework for highly selective separation of CO2from CH4,Chemical. Communications,48, 1135–1137, 2012
Huimin Liu, Dehua He*, Properties of Ni/Y2O3and Its Catalytic Performance in Methane Conversion to Syngas,International Journal of Hydrogen Energy, 36: 14447-14454, 2011
Lan Ma, Yuming Li, Dehua He*, Glycerol Hydrogenolysis to Propanediols over Ru-Re/SiO2: Acidic Property of Catalyst and Role of Re Component,Chinese Journal of Catalysis, 32: 872-876, 2011
Jinjin Li, Lan Ma, Dehua He*, Guangxing Li, Hydroformylation of 1-Octene over Amorphous Co-P-B Catalysts,Chemical Journal of Chinese Universities-Chinese,32(12): 2844-2848, 2011
Weixia Wang, Yingwei Li, Rongjun Zhang, Dehua He, Hongli Liu, Liao, Shijun Liao, Metal-organic framework as a host for synthesis of nanoscale Co3O4as an active catalyst for CO oxidation,Catalysis Communications, 12: 875-879, 2011
Yingyi Pan, Bizhen Yuan , Yingwei Li, Dehua He, Multifunctional catalysis by Pd@MIL-101: one-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal-organic framework,Chemical Communications,46: 2280-2282, 2010
Huimin Liu, Dehua He*, Physicochemical Properties of Ni/gamma-Al2O3-AlN and Effects of AlN on Catalytic Performance of Ni/gamma- Al2O3-AlN in Partial Oxidation of Methane,Journal of Physical Chemistry C, 114(32): 13716-13721, 2010.
Wei Zhou, Yuming Li, Dehua He*, Substrate influences on activity and stability of SBA-15–Pr-anchored Rh–P complex catalysts for olefin hydroformylation,Applied CatalysisA: General377: 114–120, 2010
Lan Ma, Dehua He*, Influence of catalyst pretreatment on catalytic properties and performances of Ru–Re/SiO2in glycerol hydrogenolysis to propanediols,Catalysis Today149: 148–156, 2010
Yongge Bai, Dehua He*, Shaohui Ge, Huimin Liu, Jinyao Liu, Wei Huang, Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2catalysts on synthesis of methanol via CO hydrogenation,Catalysis Today149: 111–116, 2010
Wei Zhou, Dehua He*, A facile method for promoting activities of ordered mesoporous silica-anchored Rh-P complex catalysts in 1-octene hydroformylation,Green Chemistry, 11: 1146-1154, 2009.
Lan Ma, Dehua He*, Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru-Re Bimetallic Catalysts,Topics in Catalysis, 52: 834-844, 2009.
Lan Ma, Qingrong Peng, Dehua He*, Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene,Catalysis Letters, 130: 137-146, 2009.
Wei Zhou, Dehua He*, Anchoring RhCl(CO)(PPh3)2to -PrPPh2Modified MCM-41 as Effective Catalyst for 1-Octene Hydroformylation,Catalysis Letters, 127: 437-443, 2009.
Yueqin Song, Huimin Liu, Shuqiang Liu, Dehua He*, Partial Oxidation of Methane to Syngas over Ni/Al2O3Catalysts Prepared by a Modified Sol-Gel Method,Energy & Fuels, 23: 1925-1930, 2009.
Lan Ma, Dehua He*, Effect of Rhenium Component and Preparation Methods of ZrO2Support on Catalytic Performance of Ru-Re/ZrO2for Glycerol Hydrogenolysis,Chinese Journal of Catalysis, 30: 471-478, 2009
Shuqiang Liu, Yueqin Song, Dehua He*, Zhanping Li, Partial Oxidation of Methane to Syngas over Cr2O3Catalysts,Chemical Journal of Chinese Universities-Chinese, 30: 106-112, 2009.
Lan Ma, Dehua He*, Zhanping Li, Promoting effect of rhenium on catalytic performance of Ru catalysts in hydrogenolysis of glycerol to propanediol,Catalysis Communications, 9: 2489-2495, 2008.
Wei Zhou, Dehua He*, Lengthening alkyl spacers to increase SBA-15-anchored Rh-P complex activities in 1-octene hydroformylation,Chemical Communications, 44: 5839-5841, 2008.
Shaohui Ge, Dehua He*, Zhanping Li, A Mesoporous Ce0.5Zr0.5O2Solid Solution Catalyst for CO Hydrogenation to iso-C4Hydrocarbons,Catalysis Letters, 126: 193-199, 2008.
Yingwei Li, Dehua He*, Shaohui Ge, Rongjun Zhang, Qiming Zhu, Effects of CO2on Synthesisof Isobutene and Isobutane from CO2/CO/H2Reactant Mixtures over Zirconia-based Catalysts,Applied Catalysis B: Environmental, 80: 72–80, 2008.
Yueqin Song, Dehua He*, Boqing Xu, Effects of Preparation Methods of ZrO2Support on Catalytic Performances of Ni/ZrO2Catalysts in Methane Partial Oxidation to Syngas,Applied CatalysisA: General,337:19-28, 2008.
Zhihui Zhu, Dehua He*, CO Hydrogenation to iso-C4Hydrocarbons over CeO2-TiO2Catalysts,Fuel, 870: 2229–2235, 2008.
Yingwei Li, Dehua He*, Zhihui Zhu, Qiming Zhu, Properties of Sm2O3-ZrO2Composite Oxides and Their Catalytic Performance in Isosynthesis,Applied CatalysisA: General,319: 119~127, 2007.
Qingrong Peng, DehuaHe*, Hydroformylation of mixed octenes over immobilized Co-Ph3PO/PDMS/SiO2catalyst,Catalysis Letters,115(1-2): 19-22, 2007.
Lei Shi, Guoli Dong, Dehua He*, Influence of preparation parameters on catalytic performance of samaria in isosynthesis,Catalysis Communications, 8(3):359-365, 2007.
X. Zhang, Dehua He*, Qijian Zhang,BoqingXu, Qiming Zhu, Comparative studies on direct conversion of methane to methanol/ formaldehyde over La–Co–O and ZrO2supported molybdenum oxide catalysts,Topics in Catalysis, 32(3-4):215 – 223,2005.
Yingwei Li, Dehua He*, Qiming Zhu, Xin Zhang, Boqing Xu, Effects of redox and acid-base properties on the isosynthesis over ZrO2based catalysts,Journal of Catalysis, 221:2:584-593, 2004.
Xin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Methanol from oxidation of methane over MoOx/ La-Co-oxide catalysts,Stud. Surf. Sci. Catal., 147: 541-546, 2004.
Xin Zhang,Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Selective oxidation of methane to formaldehyde over Mo/ZrO2catalysts,Applied CatalysisA: General, 249(1): 107, 2003.
Yingwei Li, Dehua He*, Qijian Zhang, Qiming Zhu, Influence of reactor materials on i-C4synthesis from CO hydrogenation over ZrO2based catalysts,Fuel Processing Technology, 83(1-3): 39-48, 2003
Qijian Zhang, Dehua He*, Xin Zhang, Qiming Zhu, Shuiliang Yao, Direct Partial Oxidation of Methane to Methanol in a Specially Designed Reactor,ACS Sym. Ser.852:Utilization of Greenhouse Gases,pp280-290, American Chemical Society Press: Washington DC, 2003.
Qijian Zhang, Dehua He*, Qiming Zhu, Recent Progress in Direct Partial Oxidation of Methane to Methanol,J.Nat.Cas.Chem., 12(2), P81-89, 2003.
Qijian Zhang, Dehua He*, Jinlu Li, Boqing Xu, Yu Liang, Qiming Zhu, Comparatively high yield methanol production from gas phase partial oxidation of methane,Applied CatalysisA: General, 224 (1-2): 201, 2002
Qijian Zhang, Dehua He*, Zhansheng Han, Boqing Xu, Qiming Zhu, Controlled Partial Oxidation of Methane to Methanol /formaldehyde over Mo-V-Cr-Bi-Si Oxide catalysts,Fuel, 81: 1599, 2002.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing. Cheng, Qiming Zhu, Influence of Acidic and Basic Properties of ZrO2Based Catalysts on Isosynthesis,Fuel, 81: 1611, 2002.
Dehua He*, Dongcheng Pang, Yu Chen, Lan Wei, Tong-en Wang, Jinyao Liu, Yan Liu, Qiming Zhu, Hydroformylation of C8Olefins Catalyzed by Rhodium-Inorganic Ammonium Salt Systems,Catalysis Communications, 3 (9): 429-433, 2002.
Yingwei Li, Dehua He*, Zhenxing Cheng, Caili Su, JinluLi, Qiming Zhu, Effect of calcium salts on isoynthesis over ZrO2catalysts,J. Molecular Catalysis A: Chemical, 175(1-2): 267, 2001.
Dehua He*,Dongcheng Pang, Yu Chen, Tong-en Wang, Yan Liu, Jinyao Liu, Qiming Zhu,Hydroformylation of Mixture of Isomeric Octenes to C9-Aldehydes Catalyzed by Rh-Phosphine Oxide Complexes,J. Molecular Catalysis A: Chemical,174(1-2): 21, 2001.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing Cheng, Qiming Zhu, Selective Formation of Isobutene from CO Hydrogenation over Zirconium Dioxide Based Catalysts,Energy and Fuels,15: 1434, 2001.
Jinyao Liu, Jiangliu Shi, Dehua He, Qijian Zhang, Xiaohui Wu, Yu Liang, Qiming Zhu, Surface active structure of ultra-fine Cu/ZrO2catalysts used for the CO2+H2to methanol reaction,Applied CatalysisA: General, 218: 113, 2001
Dehua He*, Jinyao Liu, Yan Liu, Tong-en Wang, Dongcheng Pang, Yu Chen, Yu Liang, Qiming Zhu, Effects of Ammonium Salts as Additives in Rh-Ph3PO Catalytic System on Hydroformylation of Mixed Octenes,Catalysis Letters, 73(2-4): 221, 2001.
Wei Zhou, Yuming Li, Dehua He*, Substrate influences on activity and stability of SBA-15–Pr-anchored Rh–P complex catalysts for olefin hydroformylation,Applied CatalysisA: General377: 114–120, 2010
Lan Ma, Dehua He*, Influence of catalyst pretreatment on catalytic properties and performances of Ru–Re/SiO2in glycerol hydrogenolysis to propanediols,Catalysis Today149: 148–156, 2010
Yongge Bai, Dehua He*, Shaohui Ge, Huimin Liu, Jinyao Liu, Wei Huang, Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2catalysts on synthesis of methanol via CO hydrogenation,Catalysis Today149: 111–116, 2010
Wei Zhou, Dehua He*, A facile method for promoting activities of ordered mesoporous silica-anchored Rh-P complex catalysts in 1-octene hydroformylation,Green Chemistry, 11: 1146-1154, 2009.
Lan Ma, Dehua He*, Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru-Re Bimetallic Catalysts,Topics in Catalysis, 52: 834-844, 2009.
Lan Ma, Qingrong Peng, Dehua He*, Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene,Catalysis Letters, 130: 137-146, 2009.
Wei Zhou, Dehua He*, Anchoring RhCl(CO)(PPh3)2to -PrPPh2Modified MCM-41 as Effective Catalyst for 1-Octene Hydroformylation,Catalysis Letters, 127: 437-443, 2009.
Yueqin Song, Huimin Liu, Shuqiang Liu, Dehua He*, Partial Oxidation of Methane to Syngas over Ni/Al2O3Catalysts Prepared by a Modified Sol-Gel Method,Energy & Fuels, 23: 1925-1930, 2009.
Lan Ma, Dehua He*, Effect of Rhenium Component and Preparation Methods of ZrO2Support on Catalytic Performance of Ru-Re/ZrO2for Glycerol Hydrogenolysis,Chinese Journal of Catalysis, 30: 471-478, 2009
Shuqiang Liu, Yueqin Song, Dehua He*, Zhanping Li, Partial Oxidation of Methane to Syngas over Cr2O3Catalysts,Chemical Journal of Chinese Universities-Chinese, 30: 106-112, 2009.
Lan Ma, Dehua He*, Zhanping Li, Promoting effect of rhenium on catalytic performance of Ru catalysts in hydrogenolysis of glycerol to propanediol,Catalysis Communications, 9: 2489-2495, 2008.
Wei Zhou, Dehua He*, Lengthening alkyl spacers to increase SBA-15-anchored Rh-P complex activities in 1-octene hydroformylation,Chemical Communications, 44: 5839-5841, 2008.
Shaohui Ge, Dehua He*, Zhanping Li, A Mesoporous Ce0.5Zr0.5O2Solid Solution Catalyst for CO Hydrogenation to iso-C4Hydrocarbons,Catalysis Letters, 126: 193-199, 2008.
Yingwei Li, Dehua He*, Shaohui Ge, Rongjun Zhang, Qiming Zhu, Effects of CO2on Synthesisof Isobutene and Isobutane from CO2/CO/H2Reactant Mixtures over Zirconia-based Catalysts,Applied Catalysis B: Environmental, 80: 72–80, 2008.
Yueqin Song, Dehua He*, Boqing Xu, Effects of Preparation Methods of ZrO2Support on Catalytic Performances of Ni/ZrO2Catalysts in Methane Partial Oxidation to Syngas,Applied CatalysisA: General,337:19-28, 2008.
Zhihui Zhu, Dehua He*, CO Hydrogenation to iso-C4Hydrocarbons over CeO2-TiO2Catalysts,Fuel, 870: 2229–2235, 2008.
Yingwei Li, Dehua He*, Zhihui Zhu, Qiming Zhu, Properties of Sm2O3-ZrO2Composite Oxides and Their Catalytic Performance in Isosynthesis,Applied CatalysisA: General,319: 119~127, 2007.
Qingrong Peng, DehuaHe*, Hydroformylation of mixed octenes over immobilized Co-Ph3PO/PDMS/SiO2catalyst,Catalysis Letters,115(1-2): 19-22, 2007.
Lei Shi, Guoli Dong, Dehua He*, Influence of preparation parameters on catalytic performance of samaria in isosynthesis,Catalysis Communications, 8(3):359-365, 2007.
X. Zhang, Dehua He*, Qijian Zhang,BoqingXu, Qiming Zhu, Comparative studies on direct conversion of methane to methanol/ formaldehyde over La–Co–O and ZrO2supported molybdenum oxide catalysts,Topics in Catalysis, 32(3-4):215 – 223,2005.
Yingwei Li, Dehua He*, Qiming Zhu, Xin Zhang, Boqing Xu, Effects of redox and acid-base properties on the isosynthesis over ZrO2based catalysts,Journal of Catalysis, 221:2:584-593, 2004.
Xin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Methanol from oxidation of methane over MoOx/ La-Co-oxide catalysts,Stud. Surf. Sci. Catal., 147: 541-546, 2004.
Xin Zhang,Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Selective oxidation of methane to formaldehyde over Mo/ZrO2catalysts,Applied CatalysisA: General, 249(1): 107, 2003.
Yingwei Li, Dehua He*, Qijian Zhang, Qiming Zhu, Influence of reactor materials on i-C4synthesis from CO hydrogenation over ZrO2based catalysts,Fuel Processing Technology, 83(1-3): 39-48, 2003
Qijian Zhang, Dehua He*, Xin Zhang, Qiming Zhu, Shuiliang Yao, Direct Partial Oxidation of Methane to Methanol in a Specially Designed Reactor,ACS Sym. Ser.852:Utilization of Greenhouse Gases,pp280-290, American Chemical Society Press: Washington DC, 2003.
Qijian Zhang, Dehua He*, Qiming Zhu, Recent Progress in Direct Partial Oxidation of Methane to Methanol,J.Nat.Cas.Chem., 12(2), P81-89, 2003.
Qijian Zhang, Dehua He*, Jinlu Li, Boqing Xu, Yu Liang, Qiming Zhu, Comparatively high yield methanol production from gas phase partial oxidation of methane,Applied CatalysisA: General, 224 (1-2): 201, 2002
Qijian Zhang, Dehua He*, Zhansheng Han, Boqing Xu, Qiming Zhu, Controlled Partial Oxidation of Methane to Methanol /formaldehyde over Mo-V-Cr-Bi-Si Oxide catalysts,Fuel, 81: 1599, 2002.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing. Cheng, Qiming Zhu, Influence of Acidic and Basic Properties of ZrO2Based Catalysts on Isosynthesis,Fuel, 81: 1611, 2002.
Dehua He*, Dongcheng Pang, Yu Chen, Lan Wei, Tong-en Wang, Jinyao Liu, Yan Liu, Qiming Zhu, Hydroformylation of C8Olefins Catalyzed by Rhodium-Inorganic Ammonium Salt Systems,Catalysis Communications, 3 (9): 429-433, 2002.
Yingwei Li, Dehua He*, Zhenxing Cheng, Caili Su, JinluLi, Qiming Zhu, Effect of calcium salts on isoynthesis over ZrO2catalysts,J. Molecular Catalysis A: Chemical, 175(1-2): 267, 2001.
Dehua He*,Dongcheng Pang, Yu Chen, Tong-en Wang, Yan Liu, Jinyao Liu, Qiming Zhu,Hydroformylation of Mixture of Isomeric Octenes to C9-Aldehydes Catalyzed by Rh-Phosphine Oxide Complexes,J. Molecular Catalysis A: Chemical,174(1-2): 21, 2001.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing Cheng, Qiming Zhu, Selective Formation of Isobutene from CO Hydrogenation over Zirconium Dioxide Based Catalysts,Energy and Fuels,15: 1434, 2001.
Jinyao Liu, Jiangliu Shi, Dehua He, Qijian Zhang, Xiaohui Wu, Yu Liang, Qiming Zhu, Surface active structure of ultra-fine Cu/ZrO2catalysts used for the CO2+H2to methanol reaction,Applied CatalysisA: General, 218: 113, 2001 .
Dehua He*, Jinyao Liu, Yan Liu, Tong-en Wang, Dongcheng Pang, Yu Chen, Yu Liang, Qiming Zhu, Effects of Ammonium Salts as Additives in Rh-Ph3PO Catalytic System on Hydroformylation of Mixed Octenes,Catalysis Letters, 73(2-4): 221, 2001.
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