杨金东 助理研究员

地址:北京市海淀区清华大学蒙民伟科技南楼s616室

TEl: 86-10-62787136

Email: jdyang@mail.tsinghua.edu.cn

教育背景

2005-2009年,南开大学化学系学士;2009-2014年,南开大学化学系博士;

工作履历

2014-2017年,在南开大学化学系博士后;2017年10月-至今清华大学化学系工作。

研究领域

研究兴趣:化学键能量学、键能的应用、反应机理研究。

学术成果

代表性成果:

1.Internet Bond-energy Databank (pKa and BDE)-iBonD:http://ibond.nankai.edu.cn.

2.Wu, J.-Y.; Li, Z.; Yang, J.-D.*; Cheng, J.-P.* Bonding energetics of palladium-amido/aryloxide complexes in DMSO: implications for Pd-mediated aniline activation. Angew. Chem. Int. Ed. 2020, doi: 10.1002/anie.202011313.

3.Zhang, J.; Yang, J.-D.*; Cheng, J.-P.* Recent progress in reactivity study and synthetic application of N-heterocyclic phosphorus hydrides. Natl. Sci. Rev. 2020. doi: 10.1093/nsr/nwaa253.

4.Zhang, J.; Yang, J.-D.*; Cheng, J.-P.* Diazaphosphinyl radical-catalyzed deoxygenation of α-carboxy ketones: a new protocol for chemo-selective C–O bond scission via mechanism regulation. Chem. Sci. 2020, 11, 8476-8481.

5.Zhang, J.; Yang, J.-D.*; Cheng, J.-P.* Exploiting the radical reactivity of diazaphosphinanes in hydrodehalogenations and cascade cyclizations. Chem. Sci. 2020, 11, 4786-4790.

6.Zhang, J.; Yang, J.-D.*; Cheng, J.-P.* Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications. Chem. Sci. 2020, 11, 3672-3679.

7.Luo, W.; Mao, C.; Ji, P.; Wu, J.-Y.; Yang, J.-D.*; Cheng, J.-P.* Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C–H dissociation and insight into respective solvation. Chem. Sci. 2020, 11, 3365-3370.

8.Zhang, J.; Yang, J.-D.*; Cheng, J.-P.* A Nucleophilicity scale for the reactivity of diazaphospholenium hydrides: structural insights and synthetic applications. Angew. Chem. Int. Ed. 2019, 58, 5983-5987.

9.Yang, J.-D.*; Xue, J.; Cheng, J.-P.* Understanding the role of thermodynamics in catalytic imine reductions. Chem. Soc. Rev. 2019, 48, 2913-2926.

10.Zhang, J.#; Yang, J.-D.#; Zheng, H.; Xue, X.-S.*; Mayr, H.*; Cheng, J.-P. Exploration of the synthetic potential of electrophilic trifluoromethylthiolating and difluoromethylthiolating reagents. Angew. Chem. Int. Ed. 2018, 57, 12690-12695. (joint first author)

11.Yang, J.-D.#; Ji, P.#; Xue, X.-S.; Cheng, J.-P.* Recent advances and advisable applications of bond energetics in organic chemistry. J. Am. Chem. Soc. 2018, 140, 8611-8623. (joint first author)