席婵娟博士,教授、博士生导师

联系地址:北京100084,清华大学化学系

Tel:86-10-62782695

Email:cjxi@tsinghua.edu.cn

学历:

1982.08-1986.07兰州大学化学系学士

1991.12-1994.05中国科学院兰州化学物理研究所硕士

1996.04-1999.03日本北海道大学药学部博士

1999.04-2000.03日本北海道大学触媒化学研究中心博士后

职历:

1986.07-1995.08中国科学院兰州化学物理研究所助理研究员

1995.11-1996.03日本北海道大学触媒化学研究中心外国人研究员

2000.05-2005.12清华大学化学系副教授

2005.12-清华大学化学系教授

目前讲授课程:

《物理有机化学》、《金属有机化学》

研究领域:

1.金属有机化合物的设计合成及其诱导的有机合成方法学研究

2.廉价过渡金属催化杂环化合物的合成方法学研究

3.二氧化碳的活化与转化

部分近期代表性论文和论著:

1. Zeyu Zhang, Danyun Li, Chanjuan Xi*, CO2Promoted and Nickel-Catalyzed Direct Hydroallylation of Terminal Alkynes with Allylic Alcohols: Access to 1,4-Dienes, Org. Lett. 2023, 25, 698-702.

2. Yaping Yi, Zhengning Fan, Chanjuan Xi*, Photoredox-catalyzed intermolecular dearomative trifluoromethylcarboxylation of indoles and heteroanalogues with CO2 and fluorinated radical precursors, Green Chem., 2022, 24, 7894-7899.

3. Yaping Yi, Chanjuan Xi*, Photocatalyzed sequential dearomatization/carboxylation of benzyl ohalogenated aryl ether with CO2 leading to spirocyclic carboxylic acids, Chin. J. Catal. 2022, 43, 1652-1656.

4. Zhengning Fan, Shenhao Chen, Song Zou, Chanjuan Xi*, Direct C−C Bond Formation of Allylic Alcohols with CO2 toward Carboxylic Acids by Photoredox/Nickel Dual CatalysisACS Catal., 2022, 12, 2781-2787.

5. Xuewei Luo, Bo Zhang, Chanjuan Xi*, Photoredox-catalyzed hydroxydifluoroacetylation of alkenes with FSO2CF2CO2Me and H2O: simple synthesis of CF2CO2Me-containing alcohols and difluorolactones, Green Chem., 2021, 23, 2324-2328.

6. Zhengning Fan, Yaping Yi, Shenhao Chen, Chanjuan Xi*, Visible-Light-Induced Catalyst-Free Carboxylation of Acylsilanes with Carbon Dioxide, Org. Lett., 2021, 23, 2303-2307.

7. Bo Zhang, Yaping Yi, Zhong-Qian Wu, Chao Chen*, Chanjuan Xi*, Photoredox-catalyzed dicarbofunctionalization of styrenes with amines and CO2: a convenient access to γ-amino acids, Green Chem., 2020, 22, 5961-5965.

8. Wei Hang, Yaping Yi, Chanjuan Xi*, Cp2TiCl2Catalyzed Carboxylation of Aryl Chlorides with Carbon Dioxide in the Presence of nBuMgCl, Organometallics, 2020, 39, 1476-1479.

9. Sheng Wang, Chanjuan Xi*, Recent advances in nucleophile-triggered CO2-incorporated cyclization leading to heterocycles, Chem. Soc. Rev., 2019, 48, 382-404.

10. Zhiqiang Guo, Bo Zhang, Xuehong Wei, Chanjuan Xi*Reduction of CO2 into Methylene Coupled with the Formation of CS Bonds under NaBH4/I2 System, Org. Lett. 2018, 20, 6678-6681.

11. Zhiqiang Guo, Bo Zhang, Xuehong Wei, Chanjuan Xi*1,4-Dioxane-Tuned Catalyst-Free Methylation of Amines by CO2 and NaBH4ChemSusChem 2018, 11, 2296-2299.

12. Sheng Wang, Chanjuan Xi*, Nickel-Catalyzed Arylative Carboxylation of Alkynes with Arylmagnesium Reagents and Carbon Dioxide Leading to Trisubstituted Acrylic Acids, Org. Lett. 2018, 20, 4131-4134.

13. Xiaowei Zhang, Sheng Wang, Yu Liu, and Chanjuan Xi*, Triflates-Triggered Intermolecular Cyclization of Carbodiimides Leading to 2‑Aminoquinazolinone and 2,4-Diaminoquinazoline Derivatives, Org. Lett. 2018, 20, 2148-2151.

14. Xiaoyu Yan, Chanjuan Xi*, Advances in transmetalation reactions originated from organozirconium compounds, Coord. Chem. Rev., 2017, 350, 275-284.

15. Sheng Wang, Xiaowei Zhang, Chengyao Cao, Chao Chen* and Chanjuan Xi*I2-Mediated oxidative bicyclization of 4-pentenamines to prolinol carbamates with CO2 incorporating oxyamination of the C=C bond, Green Chem., 2017, 19, 4515-4519.

16. Sheng Wang, Peng Shao, Gaixia Du, Chanjuan Xi*, MeOTf- and TBD-Mediated Carbonylation of ortho-Arylanilines with CO2 Leading to Phenanthridinones, J. Org. Chem. 2016, 81, 6672-6676.

17. Peng Shao, Sheng Wang, Chao Chen, Chanjuan Xi*, Cp2TiCl2-Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2, Org. Lett. 2016, 18, 2050-2053.

18. Xiaoyu Yan, Chanjuan Xi*, Multifaceted zirconate complexes in organic synthesis, Coord. Chem. Rev., 2016, 308, 22-31.

19. Xiaoyu, Yan, Chanjuan Xi*, Conversion of Zirconacyclopentadienes into Metalloles: Fagan-Nugent Reaction and Beyond, Acc. Chem. Res., 2015, 48, 935-946.

20. 席婵娟,邓耿,《物理有机化学:结构与原理》,高等教育出版社,2017